THE REACTIVITY OF METAL-SURFACES

被引：4

作者：

NORSKOV, JK

STOLTZE, P

NIELSEN, U

机构：

[1] HALDOR TOPSOE RES LABS,DK-2800 LYNGBY,DENMARK

[2] AARHUS UNIV,INST PHYS,DK-8000 AARHUS,DENMARK

[3] TECH UNIV DENMARK,APPL PHYS LAB,DK-2800 LYNGBY,DENMARK

来源：

CATALYSIS LETTERS | 1991年 / 9卷 / 3-4期

关键词：

HETEROGENEOUS CATALYSIS; REACTIVITY TRENDS THEORY ON METAL SURFACES; AMMONIA SYNTHESIS MODEL; D-ELECTRON CONTRIBUTION TO SURFACE BONDING;

D O I：

10.1007/BF00773175

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The relations between the microscopic description of the dynamics of chemical reactions at metal surfaces and our understanding of the activity of heterogeneous catalysts is discussed. It is shown that in some cases we start understanding some of the factors determining the catalytic activity of a given surface. Examples will be given, ranging from detailed reaction dynamics studies of simple adsorption reactions to a prediction of the trends in the ammonia synthesis rate along the transition metal series.

引用

页码：173 / 182

页数：10

共 13 条

[1] KINETIC SIMULATION OF AMMONIA-SYNTHESIS CATALYSIS [J].