ZERO KINETIC-ENERGY PHOTOELECTRON-SPECTRA OF JET-COOLED ANILINE

被引：104

作者：

SONG, XB

YANG, M

DAVIDSON, ER

REILLY, JP

机构：

[1] Department of Chemistry, Indiana University, Bloomington

来源：

JOURNAL OF CHEMICAL PHYSICS | 1993年 / 99卷 / 05期

关键词：

D O I：

10.1063/1.465131

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Zero kinetic energy electron spectra of aniline are recorded and a number of ion vibrational frequencies accurately measured. The adiabatic ionization potential of aniline is found to be 62 271 +/- 2 cm-1. Ab initio calculations provide insights into the bonding changes that take place in aniline upon ionization. Reasonable agreement between calculated and measured frequencies in the ground states of aniline neutral and ion is obtained.

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页码：3224 / 3233

页数：10

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