ASYMMETRIC ALDOL REACTIONS OF CHIRAL IMIDAZOLIDINONE FISCHER CARBENE COMPLEXES

被引：45

作者：

POWERS, TS

SHI, Y

WILSON, KJ

WULFF, WD

RHEINGOLD, AL

机构：

[1] UNIV CHICAGO,DEPT CHEM,SEARLE CHEM LAB,CHICAGO,IL 60637

[2] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 23期

关键词：

D O I：

10.1021/jo00102a003

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Highly selective aldol reactions with a-unsubstituted enolates are described for a new class of chiral carbene complexes derived from chiral imidazolidinones in which the position of the chiral center is specifically defined by the chelation of the chiral auxilliary to the metal center.

引用

页码：6882 / 6884

页数：3

共 39 条

[1] REACTION OF CHROMIUM (FISCHER) CARBENES AND SULFILIMINES
ALCAIDE, B
CASARRUBIOS, L
DOMINGUEZ, G
SIERRA, MA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (15) : 3886 - 3894
[2] EXOSELECTIVE DIELS-ALDER REACTIONS OF AMINOCARBENE COMPLEXES
ANDERSON, BA
WULFF, WD
POWERS, TS
TRIBBITT, S
RHEINGOLD, AL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) : 10784 - 10798
[3] ASYMMETRIC MICHAEL REACTIONS OF AMINOCARBENE COMPLEX ANIONS
ANDERSON, BA
WULFF, WD
RAHM, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (11) : 4602 - 4611
[4] ENANTIOSELECTIVE SYNTHESIS OF ALPHA-HYDROXY ACIDS AND BETA-HYDROXY ACIDS USING TRANS-2-PHENYLCYCLOHEXAN-1-OL AS CHIRAL AUXILIARY
BASAVAIAH, D
BHARATHI, TK
[J]. TETRAHEDRON LETTERS, 1991, 32 (28) : 3417 - 3420
[5] STEREOSELECTIVE ALDOL REACTIONS WITH ALPHA-UNSUBSTITUTED CHIRAL ENOLATES
BRAUN, M
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (01): : 24 - 37
[6] STEREOSELECTIVE TITANIUM-MEDIATED ALDOL REACTIONS OF MENTHYL ACETATE ENOLATES, AND ALLYLATIONS WITH BENZALDEHYDE
CAMBIE, RC
CODDINGTON, JM
MILBANK, JBJ
PAUSLER, MG
RUSTENHOVEN, JJ
RUTLEDGE, PS
SHAW, GL
SINKOVICH, PI
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1993, 46 (05) : 583 - 591
[7] DIASTEREOSELECTIVE ALKYLATION OF 3-ACYLIMIDAZOLIDIN-2-ONES - SYNTHESIS OF (R)-LAVANDULOL AND (S)-LAVANDULOL
CARDILLO, G
DAMICO, A
ORENA, M
SANDRI, S
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (10) : 2354 - 2356
[8] CLOSE WJ, 1950, J ORG CHEM, V15, P1131
[9] REACTIONS OF COMPLEX LIGANDS .37. ACTIVATED AMINOCARBENE COMPLEXES OF THE FISCHER TYPE - SYNTHESIS, STRUCTURE, AND ANNELATION REACTIONS
DOTZ, KH
GROTJAHN, D
HARMS, K
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (10): : 1384 - 1386
[10] CARBENE COMPLEXES IN ORGANIC-SYNTHESIS
DOTZ, KH
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (08): : 587 - 608

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