THERMAL-STABILITY OF LANGMUIR-BLODGETT AND SELF-ASSEMBLED FILMS - A POSSIBLE SCENARIO FOR ORDER-DISORDER TRANSITIONS

被引：52

作者：

ULMAN, A ^{[1
]}

机构：

[1] EASTMAN KODAK CO,CORP RES LABS,ROCHESTER,NY 14650

来源：

ADVANCED MATERIALS | 1991年 / 3卷 / 06期

关键词：

ORGANIC MONOLAYERS; MOLECULAR DYNAMICS; DISORDER MECHANISMS; FTIR;

D O I：

10.1002/adma.19910030606

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The effective design of stable, ordered organic superlattices is assisted by a thorough understanding of enthalpy and entropy contributions and molecular interactions in two dimensions. Important information in this respect can be obtained by studying the thermal stability of monolayers of long-chain organic amphiphiles. Work on both LB and SA films is reviewed and a possible explanation for thermally-induced structural events (e.g. order-disorder transitions, see figure) in molecular assemblies discussed.

引用

页码：298 / 303

页数：6

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[2]

BARRAUD A, 1975, ANN CHIM FRANCE, V10, P195

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