PHOSPHORESCENCE FROM THE TRIPLET SPIN SUBLEVELS OF A HEXANUCLEAR MOLYBDENUM(II) CHLORIDE CLUSTER ION, [MO6CL14]2- - RELATIVE RADIATIVE RATE CONSTANTS FOR EMITTING SUBLEVELS

被引：36

作者：

MIKI, H ^{[1
]}

IKEYAMA, T ^{[1
]}

SASAKI, Y ^{[1
]}

AZUMI, T ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 980,JAPAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 08期

关键词：

D O I：

10.1021/j100187a012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Phosphorescence of [Mo6Cl14]2- is investigated focusing attention on the temperature-dependent spectral shift. The relative radiative rate constants for the emitting sublevels T2u, E(u), and T(lu) are 1:5:8:100. The large radiative rate constant for the T(lu) sublevel substantiates the previous assignment of the sublevels.

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页码：3236 / 3239

页数：4

相关论文

共 9 条

[1] ELECTRONIC-STRUCTURES OF THE LOWER TRIPLET SUBLEVELS OF HEXANUCLEAR MOLYBDENUM(II) CHLORIDE CLUSTER [J].

AZUMI, T ;

SAITO, Y .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (07) :1715-1721

[2] FAR-INFRARED SPECTRA OF METAL ATOM CLUSTER COMPOUNDS .I. MO6X84+ DERIVATIVES [J].

COTTON, FA ;

WING, RM ;

ZIMMERMA.RA .

INORGANIC CHEMISTRY, 1967, 6 (01) :11-&

[3]

HARTLEY D, 1967, J CHEM SOC CHEM COMM, P912

[4] THEORY OF LIGHT ABSORPTION AND NON-RADIATIVE TRANSITIONS IN F-CENTRES [J].

HUANG, K ;

RHYS, A .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1950, 204 (1078) :406-423

[5]

MARVERICK AW, 1981, J AM CHEM SOC, V103, P1298

[6]

MARVERICK AW, 1983, J AM CHEM SOC, V105, P1878

[7] TEMPERATURE-DEPENDENCE OF THE LUMINESCENCE LIFETIME OF HEXANUCLEAR MOLYBDENUM(II) CHLORIDE CLUSTER - IDENTIFICATION OF LOWER EXCITED TRIPLET SUBLEVELS [J].

SAITO, Y ;

TANAKA, HK ;

SASAKI, Y ;

AZUMI, T .

JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (21) :4413-4415

[8] SPECTROSCOPIC STUDIES OF PHOTOCHEMICALLY IMPORTANT TRANSITION-METAL EXCITED-STATES .2. THE 1T1G, 3T1G, AND 5T2G EXCITED-STATES OF HEXAAMMINECOBALT(III) [J].

WILSON, RB ;

SOLOMON, EI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (12) :4085-4095

[9] ELECTRONIC SPECTROSCOPY AND PHOTOPHYSICS OF D4 CLUSTERS [J].

ZIETLOW, TC ;

HOPKINS, MD ;

GRAY, HB .

JOURNAL OF SOLID STATE CHEMISTRY, 1985, 57 (01) :112-119