LAMELLAR VERSUS ISOTROPIC STRUCTURES IN DILUTE PHASES OF FLUID MEMBRANES

被引：30

作者：

PORTE, G ^{[1
]}

APPELL, J ^{[1
]}

BASSEREAU, P ^{[1
]}

MARIGNAN, J ^{[1
]}

SKOURI, M ^{[1
]}

BILLARD, I ^{[1
]}

DELSANTI, M ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,SPECTROMETRIE & IMAGERIE ULTRASONORES,F-67070 STRASBOURG,FRANCE

来源：

PHYSICA A | 1991年 / 176卷 / 01期

关键词：

D O I：

10.1016/0378-4371(91)90439-J

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

In recent years, considerable attention has been focused on dilute phases of fluid membranes in surfactant systems. At the present time, the structure of two different phases have been well characterized. The lamellar phase (L-alpha) shows long range smectic order and consists of a regular stack of parallel bilayers. At high dilution, its long range order has been shown to be stabilized by the steric interaction between adjacent undulating membranes. The other phase (L3) is isotropic and shows no long range positional order. Scattering patterns and transport properties strongly suggest that its structure consists of a randomly multiconnected bilayer separating two equivalent subvolumes of solvent. We here discuss the relative stability of these two structures in connection with the elastic properties of the amphiphilic membrane. A general scaling law for the free energy of the L3 phase as function of the degree of dilution is proposed and is checked against experimental measurements of some of its static and dynamic physical properties.

引用

页码：168 / 186

页数：19

共 25 条

[21] A SYNCHROTRON X-RAY STUDY OF COMPETING UNDULATION AND ELECTROSTATIC INTERLAYER INTERACTIONS IN FLUID MULTIMEMBRANE LYOTROPIC PHASES [J].

ROUX, D ;

SAFINYA, CR .

JOURNAL DE PHYSIQUE, 1988, 49 (02) :307-318

[22] LIGHT-SCATTERING FROM A SURFACTANT SPONGE PHASE - EVIDENCE FOR A HIDDEN SYMMETRY [J].

ROUX, D ;

CATES, ME ;

OLSSON, U ;

BALL, RC ;

NALLET, F ;

BELLOCQ, AM .

EUROPHYSICS LETTERS, 1990, 11 (03) :229-234

[23] FRUSTRATION IN BILAYERS AND TOPOLOGIES OF LIQUID-CRYSTALS OF AMPHIPHILIC MOLECULES [J].

SADOC, JF ;

CHARVOLIN, J .

JOURNAL DE PHYSIQUE, 1986, 47 (04) :683-691

[24]

SAFINYA CR, 1986, PHYS REV LETT, V57, P2518

[25] DILUTE LAMELLAR AND L3 PHASES IN THE BINARY WATER-C12E5 SYSTEM [J].

STREY, R ;

SCHOMACKER, R ;

ROUX, D ;

NALLET, F ;

OLSSON, U .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (12) :2253-2261

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