A VOLTAMMETRIC STUDY OF KEGGIN-TYPE HETEROPOLYMOLYBDATE ANIONS

被引：87

作者：

MAEDA, K

HIMENO, S

OSAKAI, T

SAITO, A

HORI, T

机构：

[1] KOBE UNIV,FAC SCI,DEPT CHEM,KOBE 657,JAPAN

[2] KYOTO UNIV,GRAD SCH HUMAN & ENVIRONM STUDIES,KYOTO 60601,JAPAN

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1994年 / 364卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(93)02936-C

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The voltammetric behavior of several Keggin-type heteropolymolybdate anions, [XMo12O40]n- (X = S, P, As, V, Si, Ge; n = 2-4) at a glassy carbon (GC) electrode was investigated in acetone or acetonitrile. The one-electron reduction waves for the Keggin anions were converted into two-electron waves as a function of acid concentration. The effect of protons on the successive reduction steps was verified experimentally, and the reduction mechanism of the conversion process was elucidated.

引用

页码：149 / 154

页数：6

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