ZIRCONOCENE(ISO-BUTYL) CHLORIDE - INSITU GENERATION OF A ZIRCONOCENE(METHYL) CHLORIDE EQUIVALENT FOR USE IN ORGANIC-SYNTHESIS

被引：24

作者：

BARR, KJ ^{[1
]}

WATSON, BT ^{[1
]}

BUCHWALD, SL ^{[1
]}

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 40期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0040-4039(91)80059-F

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Zirconocene(iso-butyl) chloride, 1, which can be generated in situ from commercially available, inexpensive, and air-stable zirconocene dichloride, can function as a zirconocene(methyl) chloride equivalent.

引用

页码：5465 / 5468

页数：4

共 16 条

[1] REGIOSPECIFIC SYNTHESIS OF POLYSUBSTITUTED NAPHTHALENES AND IODOACYLNAPHTHOQUINONES VIA ZIRCONOCENE COMPLEXES OF NAPHTHALYNES
BUCHWALD, SL
KING, SM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) : 258 - 265
[2] THE TRIMETHYLPHOSPHINE ADDUCT OF THE ZIRCONOCENE BENZYNE COMPLEX - SYNTHESIS, REACTIONS, AND X-RAY CRYSTAL-STRUCTURE
BUCHWALD, SL
WATSON, BT
HUFFMAN, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (23) : 7411 - 7413
[3] SELECTIVE, ZIRCONIUM-MEDIATED CROSS-COUPLING OF ALKYNES - SYNTHESIS OF ISOMERICALLY PURE 1,3-DIENES AND 1,4-DIIODO 1,3-DIENES
BUCHWALD, SL
NIELSEN, RB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (08) : 2870 - 2874
[4] AN EFFICIENT ONE-POT METHOD FOR THE PREPARATION OF POLYSUBSTITUTED BENZOTHIOPHENES
BUCHWALD, SL
QUN, F
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (12) : 2793 - 2797
[5] ZIRCONOCENE COMPLEXES OF IMINES - GENERAL-SYNTHESIS, STRUCTURE, REACTIVITY, AND INSITU GENERATION TO PREPARE GEOMETRICALLY PURE ALLYLIC AMINES
BUCHWALD, SL
WATSON, BT
WANNAMAKER, MW
DEWAN, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (12) : 4486 - 4494
[6] SYNTHESIS OF SUBSTITUTED PYRROLES VIA ZIRCONOCENE COMPLEXES OF IMINES
BUCHWALD, SL
WANNAMAKER, MW
WATSON, BT
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (02) : 776 - 777
[7] THE ZIRCONOCENE INDUCED COUPLING OF BENZYNE WITH NITRILES - SYNTHESIS, STRUCTURE AND REACTIONS OF NOVEL AZAMETALLACYCLOPENTENES
BUCHWALD, SL
SAYERS, A
WATSON, BT
DEWAN, JC
[J]. TETRAHEDRON LETTERS, 1987, 28 (28) : 3245 - 3248
[8] A GENERAL-METHOD FOR THE PREPARATION OF ZIRCONOCENE COMPLEXES OF SUBSTITUTED BENZYNES - INSITU GENERATION, COUPLING REACTIONS, AND USE IN THE SYNTHESIS OF POLYFUNCTIONALIZED AROMATIC-COMPOUNDS
BUCHWALD, SL
WATSON, BT
LUM, RT
NUGENT, WA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (23) : 7137 - 7141
[9] BUCHWALD SL, 1988, CHEM REV, V7, P1044
[10] BUCHWALD SL, 1990, 199TH NAT M AM JCHEM

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