SENSORS FOR ORGANIC-SOLVENT DETECTION IN THE PPM RANGE BASED ON DIOXO[6.1.6.1]PARACYCLOPHANES - FROM MOLECULAR MODELING TO ANALYTE RECOGNITION

被引：28

作者：

DICKERT, FL ^{[1
]}

HAUNSCHILD, A ^{[1
]}

REIF, M ^{[1
]}

BULST, WE ^{[1
]}

机构：

[1] SIEMENS AG,ZFE ST KM1,W-8000 MUNICH 83,GERMANY

来源：

ADVANCED MATERIALS | 1993年 / 5卷 / 04期

关键词：

D O I：

10.1002/adma.19930050410

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Communication: Hydrophobic coatings for mass-sensitive sensor devices, which yield a negligible water cross sensitivity, are the aim of the reported research. Molecular modeling was used to gain an understanding of the binding mechanism of some solvent molecules with a tetraazaparacyclophane containing alkyl substituents at the amino bridge-heads (CPO44VAL)-the figure shows the calculated geometry of the benzene complex of CPO44VAL. The theoretical results were then compared with the actual performance of CPO44VAL in devices.

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页码：277 / 279

页数：3

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