SELECTIVE OXIDATIVE CLEAVAGE OF 1,2-DIMETHOXYARENES TO MUCONIC DIESTERS CATALYZED BY AN IRON BETA-SULFONATED-TETRAKIS(PENTAFLUOROPHENYL)PORPHYRIN

被引：13

作者：

ARTAUD, I ^{[1
]}

GRENNBERG, H ^{[1
]}

MANSUY, D ^{[1
]}

机构：

[1] UNIV UPPSALA,INST CHEM,S-75121 UPPSALA,SWEDEN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 15期

关键词：

D O I：

10.1039/c39920001036

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The water-soluble iron(III)[TF5PS4P = meso-tetrakis(pentafluorophenyl)-beta-tetrasulfonatoporphyrin] catalyses the selective oxidation, by magnesium monoperoxyphthalate (or H2O2), of 1,2-dimethoxyarenes bearing an electron-withdrawing substituent (CN, CHO, COR) to muconic dimethyl esters which are formed in 30-40% yield and are the only reaction products obtained after CH2Cl2 extraction.

引用

页码：1036 / 1038

页数：3

共 11 条

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