ION MOLECULE REACTIONS IN A MIXTURE OF AR AND H2 - HIGH-PRESSURE MASS-SPECTROMETRY AND QUANTUM CHEMICAL CALCULATIONS

被引：25

作者：

HVISTENDAHL, G

SAASTAD, OW

UGGERUD, E

机构：

[1] Department of Chemistry, University of Oslo, N-0315 Oslo 3

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES | 1990年 / 98卷 / 02期

关键词：

D O I：

10.1016/0168-1176(90)85016-U

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The ion/molecule reactions taking place as the result of electron impact on a 100:1 mixture of Ar and H2 have been stidied by pulsed electron beam high pressure mass spectrometry. It is shown that ArH+ hydrogen bonds to Ar to give (ArHAr)+ and to H2 to give ArH+3. The bond to H2 is stronger by 20 ± 13 kJ mol-1. The experimental data agree well with results from high level ab initio quantum chemical calculation. © 1990.

引用

页码：167 / 177

页数：11

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