CONJUGATE REDUCTION AND REDUCTIVE ALKYLATION OF ALPHA,BETA-UNSATURATED CYCLOHEXENONES USING POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE

被引：76

作者：

GANEM, B ^{[1
]}

机构：

[1] CORNELL UNIV,DEPT CHEM,ITHACA,NY 14853

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1975年 / 40卷 / 01期

关键词：

D O I：

10.1021/jo00889a047

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：146 / 147

页数：2

共 8 条

[1] RAPID QUANTITATIVE REACTION OF POTASSIUM HYDRIDE WITH WEAK LEWIS ACIDS - HIGHLY CONVENIENT NEW ROUTE TO HINDERED COMPLEX BOROHYDRIDES
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[2] LITHIUM TRI-SEC-BUTYLBOROHYDRIDE - NEW REAGENT FOR REDUCTION OF CYCLIC AND BICYCLIC KETONES WITH SUPER STEREOSELECTIVITY - REMARKABLY SIMPLE AND PRACTICAL PROCEDURE FOR CONVERSION OF KETONES TO ALCOHOLS IN EXCEPTIONALLY HIGH STEREOCHEMICAL PURITY
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[3] EFFICIENT GENERATION OF 15S CONFIGURATION IN PROSTAGLANDIN SYNTHESIS - ATTRACTIVE INTERACTIONS IN STEREOCHEMICAL CONTROL OF CARBONYL REDUCTION
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[4] METHOD FOR REGIOSPECIFIC SYNTHESIS OF MANNICH BASES - REACTION OF ENOL BORINATES WITH DIMETHYL(METHYLENE) AMMONIUM IODIDE
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (02) : 602 - 603
[5] OCCURRENCE OF 1,2-OR 1,4-ADDITION IN REDUCTION OF SOME ALPHABETA-UNSATURATED KETONES WITH METAL HYDRIDES
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[6] VINYLOXYBORANES AS SYNTHETIC INTERMEDIATES
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (03) : 967 - 968
[7] TRANSFER REACTIONS INVOLVING BORON .22. POSITION-SPECIFIC PREPARATION OF DIALKYLATED KETONES FROM DIAZO KETONES AND METHYL VINYL KETONE VIA VINYLOXYBORANES
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1971, 36 (13) : 1790 - &
[8] ALPHA-ALKYLATION OF ENOLATES FROM LITHIUM-AMMONIA REDUCTION OF ALPHA,BETA-UNSATURATED KETONES
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (13) : 2965 - &

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