A STEREOSELECTIVE APPROACH TO THE ANGUCYCLINONE ANTIBIOTICS - A TOTAL SYNTHESIS OF THE C-1 EPIMER OF (+/-)-RUBIGINONE B1

被引：36

作者：

LARSEN, DS

OSHEA, MD

机构：

[1] University of Otago, Dunedin

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 08期

关键词：

D O I：

10.1016/S0040-4039(00)91799-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A stereoselective Lewis acid-promoted cycloaddition reaction of 5-hydroxy-1,4-naphthoquinone and dienol (12) gave a key intermediate (14) which was transformed into the title compound (18) in 35% overall yield.

引用

页码：1373 / 1376

页数：4

共 11 条

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