ELECTRON-AFFINITIES AND GAS-PHASE ACIDITIES OF ORGANOGERMANIUM AND ORGANOTIN COMPOUNDS

被引：10

作者：

BRINKMAN, EA ^{[1
]}

SALOMON, K ^{[1
]}

TUMAS, W ^{[1
]}

BRAUMAN, JI ^{[1
]}

机构：

[1] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1995年 / 117卷 / 17期

关键词：

D O I：

10.1021/ja00122a022

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electron affinities have been measured for trimethylgermanium and trimethyltin radicals as 31.9 +/- 0.7 and 39.2 +/- 1.5 kcal/mol, respectively, using electron photodetachment spectroscopy. The acidities (Delta H degrees(acid)) for the corresponding hydrides (Me(3)GeH and Me(3)SnH) have been bracketed as 361.5 +/- 2.8 and 349 +/- 2 kcal/mol. From the electron affinities and the acidities, the D degrees(Me(3)MH) are derived as 79.8 +/- 3.5 and 75 +/- 3.5 kcal/mol, respectively. These physical properties are compared with the properties of the group IVA through group VIIA binary hydrides and methyl-substituted compounds. The electron affinities of the group IVA compounds do not conform to the regular pattern; some of the reasons for this are discussed.

引用

页码：4905 / 4910

页数：6

共 59 条

[1] VIBRATIONAL DISTRIBUTIONS AND RATE CONSTANTS FROM REACTIONS OF OXYGEN-ATOMS WITH HL, GEH4, SIH4, H2SE, AND H2S [J].