THE ELECTROCHEMICAL POLYMERIZATION OF METHYLENE-BLUE AND BIOELECTROCHEMICAL ACTIVITY OF THE RESULTING FILM

被引：131

作者：

KARYAKIN, AA

STRAKHOVA, AK

KARYAKINA, EE

VARFOLOMEYEV, SD

YATSIMIRSKY, AK

机构：

[1] Chemical Department, M.V. Lomonosov Moscow State University

来源：

BIOELECTROCHEMISTRY AND BIOENERGETICS | 1993年 / 32卷 / 01期

关键词：

D O I：

10.1016/0302-4598(93)80018-P

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The electrochemical polymerization of methylene blue in aqueous solutions and the properties of the resulting films were investigated. The films possessed monomer-type redox activity, and a new redox couple, responsible for the semiconducting properties of the polymer, was observed. The growth rate of the film increased in basic media. The influence of hydroxide ions can be simulated in terms of both nucleophilic catalysis and a shielding effect. The bioelectrochemical oxidation of glucose at methylene blue semiconductor films in the presence of glucose oxidase was observed.

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页码：35 / 43

页数：9

相关论文

共 30 条

[1] ELECTROCHEMICAL IMMOBILIZATION OF ENZYMES .1. THEORY [J].

BARTLETT, PN ;

WHITAKER, RG .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 224 (1-2) :27-35

[2]

CHAPLIN MF, 1991, P C BIOTECH UK

[3]

Clark W. M., 1925, PUBLIC HLTH REP, V40, P1131

[4] AN ELECTROCHEMICALLY GROWN POLYMER AS AN IMMOBILIZATION MATRIX FOR WHOLE CELLS - APPLICATION IN AN AMPEROMETRIC DOPAMINE SENSOR [J].

DESHPANDE, MV ;

HALL, EAH .

BIOSENSORS & BIOELECTRONICS, 1990, 5 (06) :431-448

[5] ELECTROCHEMICAL POLYMERIZATION OF PYRROLE [J].

DIAZ, AF ;

KANAZAWA, KK ;

GARDINI, GP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (14) :635-636

[6] ELECTROACTIVE POLYANILINE FILMS [J].

DIAZ, AF ;

LOGAN, JA .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1980, 111 (01) :111-114

[7] ENZYME ENTRAPMENT IN ELECTRICALLY CONDUCTING POLYMERS - IMMOBILIZATION OF GLUCOSE-OXIDASE IN POLYPYRROLE AND ITS APPLICATION IN AMPEROMETRIC GLUCOSE SENSORS [J].

FOULDS, NC ;

LOWE, CR .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 :1259-1264

[8] IMMOBILIZATION OF GLUCOSE-OXIDASE IN FERROCENE-MODIFIED PYRROLE POLYMERS [J].

FOULDS, NC ;

LOWE, CR .

ANALYTICAL CHEMISTRY, 1988, 60 (22) :2473-2478

[9] ACTIVATION AND DEACTIVATION OF GLASSY-CARBON ELECTRODES [J].

HU, IF ;

KARWEIK, DH ;

KUWANA, T .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1985, 188 (1-2) :59-72

[10] GLUCOSE SENSITIVITY OF POLYPYRROLE FILMS CONTAINING IMMOBILIZED GLUCOSE-OXIDASE AND HYDROQUINONESULFONATE IONS [J].

KAJIYA, Y ;

SUGAI, H ;

IWAKURA, C ;

YONEYAMA, H .

ANALYTICAL CHEMISTRY, 1991, 63 (01) :49-54