THE TEMPLATE-DIRECTED SYNTHESIS OF A [2]ROTAXANE

被引：71

作者：

ASHTON, PR ^{[1
]}

GROGNUZ, M ^{[1
]}

SLAWIN, AMZ ^{[1
]}

STODDART, JF ^{[1
]}

WILLIAMS, DJ ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,DEPT CHEM,LONDON SW7 2AY,ENGLAND

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 43期

关键词：

D O I：

10.1016/0040-4039(91)80797-A

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

X-Ray crystallography, FABMS, and H-1 and C-13 NMR spectroscopy have all been employed in the characterisation of a self-assembled [2]rotaxane composed of (i) a polyether chain intercepted by a centrally-located pi-electron rich hydroquinol ring and terminated by adamantoyl groups and (ii) a tetracationic cyclophane constructed by two pi-electron deficient bipyridinium units linked by paraphenylenedimethyl residues.

引用

页码：6235 / 6238

页数：4

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