GIGANTIC LATTICES AND GIGANTIC NONCRYSTALLINE CLUSTERS IN GLASSES

被引：11

作者：

DEMBOVSKY, SA

KOZMIN, PA

机构：

[1] Institute of General and Inorganic Chemistry, Leninsky Pr. 3I

来源：

SOLID STATE COMMUNICATIONS | 1993年 / 86卷 / 10期

关键词：

D O I：

10.1016/0038-1098(93)90827-A

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The phenomenon of unusual light scattering observed earlier during exposure of the bulk glasses As2S3 and GeS2 to polarized light with hupsilon < E(g) which causes- optical anisotropy and gyrotropy in the samples is considered here as the structural diffraction. For the first time the formation of gigantic non-crystalline clusters (GNC) of the micrometer size and gigantic lattices due to the GNC regular packing is established. It is shown that the existence of a dynamic subsystem consisting of soft atomic configurations in the form of three-centre bonds (TCB) in addition to the basic subsystem of rigid covalent bonds is a necessary condition for the creation of GNC which have collective TCB on their mobile boundaries.

引用

页码：623 / 626

页数：4

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