THE EFFECTIVENESS OF SOLVENTS AS HYDROGEN-BOND DONORS

被引：192

作者：

MARCUS, Y

机构：

[1] Department of Inorganic and Analytical Chemistry, The Hebrew University of Jerusalem, Jerusalem

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1991年 / 20卷 / 09期

关键词：

SOLVENT POLARITY; HYDROGEN BONDING; ALPHA-SCALE; ET SCALE; Z SCALE; AN SCALE;

D O I：

10.1007/BF01074953

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Taft and Kamlet's alpha-scale of solvent hydrogen bond donation ability is reexamined with regard to its correlations with three widely used polarity scales: Dimroth and Reichardt's E(T)(30), Kosower's Z and Mayer's A(N), as well as with the alpha-m values of the solvents when present as monomeric solutes. The correlation with E(T) serves to extend the solvent alpha-scale according to the expression: alpha = [E(T) - E(T-degrees) - s(pi* + d-delta) - b-beta] / a where s, b, a, d, pi*, delta, and beta have their usual meanings in the context of the Taft and Kamlet scales.

引用

页码：929 / 944

页数：16

共 19 条

[1] HYDROGEN-BONDING .8. POSSIBLE EQUIVALENCE OF SOLUTE AND SOLVENT SCALES OF HYDROGEN-BOND BASICITY OF NON-ASSOCIATED COMPOUNDS
ABRAHAM, MH
BUIST, GJ
GRELLIER, PL
MCGILL, RA
PRIOR, D
OLIVER, S
TURNER, E
MORRIS, JJ
TAYLOR, PJ
NICOLET, P
MARIA, PC
GAL, JF
ABBOUD, JLM
DOHERTY, RM
KAMLET, MJ
SHUELY, WJ
TAFT, RW
[J]. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1989, 2 (07) : 540 - 552
[2] HYDROGEN-BONDING .7. A SCALE OF SOLUTE HYDROGEN-BOND ACIDITY BASED ON LOG K-VALUES FOR COMPLEXATION IN TETRACHLOROMETHANE
ABRAHAM, MH
GRELLIER, PL
PRIOR, DV
DUCE, PP
MORRIS, JJ
TAYLOR, PJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1989, (06): : 699 - 711
[3] DIMROTH K, 1966, LIEBIGS ANN CHEM, V661, P1
[4] ANION SOLVATION PROPERTIES OF PROTIC SOLVENTS .1. SPECTROSCOPIC STUDY
HORMADALY, J
MARCUS, Y
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1979, 83 (22) : 2843 - 2848
[5] LINEAR SOLVATION ENERGY RELATIONSHIPS .23. A COMPREHENSIVE COLLECTION OF THE SOLVATOCHROMIC PARAMETERS, PI-STAR, ALPHA AND BETA, AND SOME METHODS FOR SIMPLIFYING THE GENERALIZED SOLVATOCHROMIC EQUATION
KAMLET, MJ
ABBOUD, JLM
ABRAHAM, MH
TAFT, RW
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (17) : 2877 - 2887
[6] SOLVATOCHROMIC COMPARISON METHOD .1. BETA-SCALE OF SOLVENT HYDROGEN-BOND ACCEPTOR (HBA) BASICITIES
KAMLET, MJ
TAFT, RW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (02) : 377 - 383
[7] LINEAR SOLVATION ENERGY RELATIONSHIPS .46. AN IMPROVED EQUATION FOR CORRELATION AND PREDICTION OF OCTANOL WATER PARTITION-COEFFICIENTS OF ORGANIC NONELECTROLYTES (INCLUDING STRONG HYDROGEN-BOND DONOR SOLUTES)
KAMLET, MJ
DOHERTY, RM
ABRAHAM, MH
MARCUS, Y
TAFT, RW
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (18) : 5244 - 5255
[8] LINEAR SOLVATION ENERGY RELATIONSHIPS - LOCAL EMPIRICAL RULES - OR FUNDAMENTAL LAWS OF CHEMISTRY - A REPLY TO THE CHEMOMETRICIANS
KAMLET, MJ
TAFT, RW
[J]. ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1985, 39 (08): : 611 - 628
[9] KOSOWER EM, 1958, J AM CHEM SOC, V80, P5253
[10] KOSOWER EM, 1968, INTRO PHYSICAL ORGAN

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