TRANSLATIONAL ENERGY-DEPENDENCE OF GAS-PHASE REACTIONS OF HALIDES WITH HALOGENATED ALKANES

被引：14

作者：

HOP, CECA

MCMAHON, TB

机构：

[1] UNIV GUELPH,DEPT CHEM,GUELPH N1G 2W1,ONTARIO,CANADA

[2] UNIV GUELPH,GUELPH WATERLOO CTR GRAD WORK CHEM,GUELPH N1G 2W1,ONTARIO,CANADA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1991年 / 95卷 / 26期

关键词：

D O I：

10.1021/j100179a018

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The gas-phase bimolecular nucleophilic substitution reactions Br- + CCl4 --> BrCCl3 + Cl-, Br- + CF2Cl2 --> BrCF2Cl + Cl-, and Cl- + CBr4 --> ClCBr3 + Br- were studied as a function of the center-of-mass energy with Fourier transform ion cyclotron resonance spectrometry. From the energy dependence and the threshold energies of these reactions, conclusions were drawn concerning the mechanism involved.

引用

页码：10582 / 10586

页数：5

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