MEASUREMENT OF THE STATE-SPECIFIC DIFFERENTIAL CROSS-SECTION FOR THE H+D-2-]HD(V'=4, J'=3)+D REACTION AT A COLLISION ENERGY OF 2.2 EV

被引:54
作者
XU, H
SHAFERRAY, NE
MERKT, F
HUGHES, DJ
SPRINGER, M
TUCKETT, RP
ZARE, RN
机构
[1] UNIV OKLAHOMA,DEPT PHYS & ASTRON,NORMAN,OK 73019
[2] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND
关键词
D O I
10.1063/1.470604
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
HI and D-2 are coexpanded into a vacuum chamber. The photolysis of HI at 212.8 nm-initiates the H+D-2 reaction. The HD(v=4,J'=3) velocity distribution is determined by analyzing the time-of-flight profile of HD+ ions produced by delayed pulsed field ionization of long-lived Rydberg states. The angular distribution is deduced using the law of cosines (photoloc technique). (C) 1995 American Institute of Physics.
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页码:5157 / 5160
页数:4
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