FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .17. REACTIVITY OF CARBON CARBON DOUBLE-BONDS

被引：26

作者：

BARTON, DHR ^{[1
]}

LEE, KW ^{[1
]}

MEHL, W ^{[1
]}

OZBALIK, N ^{[1
]}

ZHANG, L ^{[1
]}

机构：

[1] KOREA RES INST CHEM TECHNOL,CHUNGNAM 305606,SOUTH KOREA

来源：

TETRAHEDRON | 1990年 / 46卷 / 11期

关键词：

D O I：

10.1016/S0040-4020(01)90511-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Gif oxidation systems cleave methylidene olefins into the ketone or aldehyde and formaldehyde. This is considered to be a further manifestation of an Vfe oxenoid species. Similarly, more substituted olefins are oxidized to the corresponding unsaturated ketones or aldehydes. The oxidation of limonene afforded the ketone 24 resulting from methylene cleavage and racemic carvone 25. The latter is considered to originate from a symmetrical π-allyl complex of iron. © 1990.

引用

页码：3753 / 3768

页数：16

共 39 条

[1] ATTEMPTS TO FIND NEW CHEMOTHERAPEUTIC AMIDINES .9. DERIVATIVES OF 1-1-DIPHENYLETHYLENE AND NAPHTHALENE
ASHLEY, JN
GROVE, JF
HENSHALL, T
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1948, (MAR): : 261 - 264
[2] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .10. A COMPARATIVE-STUDY OF CHEMICAL AND ELECTROCHEMICAL PROCESSES (GIF AND GIF-ORSAY SYSTEMS) IN PYRIDINE, IN ACETONE AND IN PYRIDINE-CO-SOLVENT MIXTURES
BALAVOINE, G
BARTON, DHR
BOIVIN, J
GREF, A
LECOUPANEC, P
OZBALIK, N
PESTANA, JAX
RIVIERE, H
[J]. TETRAHEDRON, 1988, 44 (04) : 1091 - 1106
[3] Barton D. H. R., UNPUB
[4] NEW AND IMPROVED METHODS FOR THE RADICAL DECARBOXYLATION OF ACIDS
BARTON, DHR
CRICH, D
MOTHERWELL, WB
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (17) : 939 - 941
[5] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .11. OXIDATION OF CEDROL, BETA-EUDESMOL AND GAMMA-EUDESMOL, SCLAREOL, MANOYL OXIDE, 1,9-DIDEOXYFORSKOLIN, METHYL TRANS-DIHYDROJASMONATE, AND TETRAHYDROLINALOOL BY THE GIF SYSTEM
BARTON, DHR
BELOEIL, JC
BILLION, A
BOIVIN, J
LALLEMAND, JY
LELANDAIS, P
MERGUI, S
[J]. HELVETICA CHIMICA ACTA, 1987, 70 (08) : 2187 - 2200
[6] A NEW PROCEDURE FOR THE OXIDATION OF SATURATED-HYDROCARBONS
BARTON, DHR
GASTIGER, MJ
MOTHERWELL, WB
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (01) : 41 - 43
[7] BARTON DHR, 1986, NEW J CHEM, V10, P387
[8] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .6. SELECTIVE OXIDATION OF STEROIDS AND RELATED-COMPOUNDS
BARTON, DHR
BOIVIN, J
HILL, CH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (10): : 1797 - 1804
[9] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .14. FURTHER-STUDIES ON THE MECHANISM OF GIF-TYPE SYSTEMS
BARTON, DHR
HALLEY, F
OZBALIK, N
SCHMITT, M
YOUNG, E
BALAVOINE, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (18) : 7144 - 7149
[10] RADICAL REACTIONS BASED ON THE THIONE FUNCTION
BARTON, DHR
OZBALIK, N
[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1989, 43 (3-4): : 349 - 366

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