NOVEL LOW-TEMPERATURE ROUTE TO KNOWN (MNS AND FES2) AND NEW (CRS3, MOS4 AND WS5) TRANSITION-METAL SULFIDES

被引：41

作者：

RICE, DA ^{[1
]}

HIBBLE, SJ ^{[1
]}

ALMOND, MJ ^{[1
]}

MOHAMMAD, KAH ^{[1
]}

PEARSE, SP ^{[1
]}

机构：

[1] UNIV READING,DEPT CHEM,POB 224,READING RG6 2AD,BERKS,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1992年 / 2卷 / 08期

关键词：

TRANSITION-METAL SULFIDE; LOW-TEMPERATURE SYNTHESIS;

D O I：

10.1039/jm9920200895

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of the transition-metal carbonyls, Mn2(CO)10, Fe(CO)5 or M(CO)6 (M = Cr, Mo or W) with sulfur in 1,2-dichlorobenzene yields polycrystalline MnS (alabandite), FeS2 (marcarsite), and three new amorphous sulfur-rich sulfides CrS3, MoS4 and WS5.

引用

页码：895 / 896

页数：2

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