THE FIRST DECAISOPROPYLMETALLOCENE - ONE-POT SYNTHESIS OF [RH(C(5)IPR(5))(2)]PF6 FROM [RH(C(5)ME(5))(2)]PF6 BY FORMATION OF 20 CARBON-CARBON BONDS

被引：25

作者：

BUCHHOLZ, D ^{[1
]}

ASTRUC, D ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,CHIM ORGAN & ORGANOMET LAB,CNRS,URA 35,F-33405 TALENCE,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 15-16期

关键词：

D O I：

10.1002/anie.199416371

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Only with a second‐row transition metal as the central atom can decamethylmetallocenes [M(C5Me5)2]+ be fully permethylated to give decaisopropylmetallocenes 1. The corresponding rhodium complex, M = Rh, was isolated in 55% yield; in the analogous reaction of the cobalt sandwich complex, a maximum of 14 methyl groups were introduced. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1637 / 1639

页数：3

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