DI-MU-FLUORO-BIS[BIS(DIMETHYL-SULFOXIDE)-TRIFLUOROZIRCONIUM(IV)]

被引：19

作者：

ALCOCK, NW

ERRINGTON, W

GOLBY, SL

PATTERSON, SMC

WALLBRIDGE, MGH

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193008054

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [ZrF4(C2H6OS)2]2, is a centrosymmetric fluorine-bridged dimer. The seven-coordinate Zr atoms are in a pentagonal bipyramidal environment with F atoms above and below the pentagonal plane. The average Zr-F bridging distance of 2.167 (4) angstrom is significantly longer than the terminal distances which range from 1.973 (4) to 2.001 (4) angstrom.

引用

页码：226 / 227

页数：2

共 9 条

[1] FLUORO-COMPLEXES OF GROUP IVA ELEMENTS - METAL-HALOGEN VIBRATIONAL FREQUENCIES
CLARK, RJH
ERRINGTON, W
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (02): : 258 - +
[2] ENTHALPY OF REACTION OF DIMETHYLSULFOXIDE WITH ZIRCONIUM, HAFNIUM AND TIN TETRAHALIDES
MAKHIJA, R
WESTLAND, AD
[J]. INORGANICA CHIMICA ACTA, 1978, 29 (02) : L269 - L271
[3] STEREOCHEMISTRY OF COMPLEXES BASED ON METAL TETRAFLUORIDES
MUETTERTIES, EL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (05) : 1082 - 1087
[4] Reynolds W. L, 1970, PROGR INORGANIC CHEM, V12, P1
[5] DIMETHYLSULFOXIDE AS A SOLVENT FOR INORGANIC COMPOUNDS
SCHLAFER, HL
SCHAFFERNICHT, W
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1960, 72 (17) : 618 - 626
[6] UBER DIMETHYLSULFOXIDVERBINDUNGEN VON TETRAHALOGENIDEN MX4(M=TI ZR HF X=CL BR)
SCHLAFER, HL
WILLE, HW
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1965, 340 (1-2): : 40 - &
[7] PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES
SHELDRICK, GM
[J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 : 467 - 473
[8] SHELDRICK GM, 1991, SHELXTL PLUS
[9] SHELDRICK GM, 1993, UNPUB J APPL CRYST

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