ABSORPTION-SPECTRA OF CHARGED OLIGO(PHENYLENEVINYLENE)S - ON THE DETECTION OF POLARONIC AND BIPOLARONIC STATES

被引:72
作者
SCHENK, R
GREGORIUS, H
MULLEN, K
机构
[1] Max-Planck-Institut Für Polymerforschung, Mainz, W-6500
关键词
D O I
10.1002/adma.19910031007
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Communication: The effective conjugation length of poly(phenylenevinylene) an important conducting polymer, can be estimated by extrapolation of the results of UV/VIS/NIR studies of the radical anions and dianions of the soluble, well-characterized oligo(phenylenevinylene)s shown in the figure. This information, in turn, is usefull in describing the mechanism of conduction in the polymer.
引用
收藏
页码:492 / 493
页数:2
相关论文
共 16 条
[1]   STRUCTURAL BASIS FOR SEMICONDUCTING AND METALLIC POLYMER DOPANT SYSTEMS [J].
BAUGHMAN, RH ;
BREDAS, JL ;
CHANCE, RR ;
ELSENBAUMER, RL ;
SHACKLETTE, LW .
CHEMICAL REVIEWS, 1982, 82 (02) :209-222
[2]   CHARACTERIZATION OF POLY(PHENYLENEVINYLENE) BY INFRARED AND OPTICAL-ABSORPTION [J].
BRADLEY, DDC ;
EVANS, GP ;
FRIEND, RH .
SYNTHETIC METALS, 1987, 17 (1-3) :651-656
[3]  
BRENDEL P, IN PRESS SYNTH MET
[4]   PHOTOEXCITATION IN CONJUGATED POLYMERS [J].
FRIEND, RH ;
BRADLEY, DDC ;
TOWNSEND, PD .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1987, 20 (11) :1367-1384
[5]   THE CHARGE STORAGE MECHANISM OF CONDUCTING POLYMERS - A VOLTAMMETRIC STUDY ON DEFINED SOLUBLE OLIGOMERS OF THE PHENYLENE-VINYLENE TYPE [J].
HEINZE, J ;
MORTENSEN, J ;
MULLEN, K ;
SCHENK, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (09) :701-703
[6]  
Hoijtink, 1959, Z PHYS CHEM, V20, P1
[7]  
HORHOLD HH, 1976, POLYKONDENSATIONSPRO, V5, P171
[8]  
HORHOLD HH, 1984, WISS BER AKAD WISS D, V29, P87
[9]  
JONSON RC, 1973, PADE APPROXIMATION T, P53
[10]  
MURASE I, 1984, POLYM COMMUN, V25, P327