PH-DEPENDENCE OF THE BAKERS-YEAST CONVERSION OF 4-BENZOYLOXY-CROTONALDEHYDE INTO THE 1-BENZOATE OF (2R) 1,2,4-BUTANETRIOL

被引:1
作者
FUGANTI, C
LANATI, S
SERVI, S
TAGLIANI, A
机构
[1] Dipartimento di Chimica, Politecnico di Milano, CNR Centro di Studio delle Sostanze Organiche Naturali, 20131 Milano
关键词
D O I
10.1016/S0960-894X(01)80764-2
中图分类号
R914 [药物化学];
学科分类号
100701 ;
摘要
In the baker's yeast mediated conversion of 4-benzoyloxycrotonaldehyde (5) into the 1-benzoate of (2R) 1,2,4-butanetriol (7) there is a marked dependence of the ee values from the pH, nearly racemic materials being obtained over pH 4.6.
引用
收藏
页码:2785 / 2788
页数:4
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