(C6F5NGAME)4 AND (C6F5NINME)4 - THE 1ST GALLIUM NITROGEN AND INDIUM NITROGEN-COMPOUNDS WITH CUBANE STRUCTURES

被引：42

作者：

BELGARDT, T ^{[1
]}

ROESKY, HW ^{[1
]}

NOLTEMEYER, M ^{[1
]}

SCHMIDT, HG ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,D-37077 GOTTINGEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 07期

关键词：

D O I：

10.1002/anie.199310561

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ga4N4 and In4N4 cubes are the central structural units of the tetrameric imino-metalanes 1 and 2, respectively. These are accessible from pentafluoroaniline and trimethylmetalane by methane elimination. Characteristic for these compounds is the increase in the distortion of the cubane framework with the increasing mass of the metal atom.

引用

页码：1056 / 1058

页数：3

共 7 条

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