SILICON ANALOGS OF GRIGNARD COMPOUNDS - SYNTHESIS AND STRUCTURE OF AMINE-STABILIZED TRIMETHYLSILYLMAGNESIUM HALIDES

被引：30

作者：

GODDARD, R

KRUGER, C

RAMADAN, NA

RITTER, A

机构：

[1] MAX PLANCK INST STRAHLENCHEM, D-45413 MULHEIM, GERMANY

[2] MAX PLANCK INST KOHLENFORSCH, D-45470 MULHEIM, GERMANY

[3] EGYPTIAN PETR RES INST, CAIRO, EGYPT

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1995年 / 34卷 / 09期

关键词：

GRIGNARD COMPOUNDS; MAGNESIUM COMPOUNDS; SILICON COMPOUNDS; STRUCTURE ELUCIDATION;

D O I：

10.1002/anie.199510301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A SiMg bond replaces the CMg bond of standard Grignard reagents in the title compounds 1 and 2. They are synthesized from Me3SiHal and pyrophoric magnesium in the presence of complexing amine ligands. The crystal structures of 1 and 2 reveal that 1 exists in the solid state as an associated complex, whereas 2 is monomeric and has a pentacoordinate Mg atom. (Formula Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：1030 / 1032

页数：3

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