MORE ON ADAMANTENE

被引：21

作者：

BIAN, NY ^{[1
]}

JONES, M ^{[1
]}

机构：

[1] PRINCETON UNIV, DEPT CHEM, PRINCETON, NJ 08544 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1995年 / 117卷 / 35期

关键词：

D O I：

10.1021/ja00140a009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

At high dilution and temperature adamantene undergoes a retro Diels-Alder cycloaddition to a triene, as well as retro-insertion reactions to give carbenes. 1,2-Diiodoadamantane and 3-diiodomethylnoradamantane react with methyllithium in the gas phase to give adamantene, which is efficiently reduced to adamantane under these conditions. Addition of adamantene to butadiene occurs in 4 + 2 and 2 + 2 fashion.

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页码：8957 / 8961

页数：5

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