A 1,6-DIPHOSPHA-1,2,4,5-HEXATETRAENE, SYNTHESIS AND RING-CLOSURE REACTIONS TO CYCLOBUTENES

被引：50

作者：

MARKL, G ^{[1
]}

KREITMEIER, P ^{[1
]}

NOTH, H ^{[1
]}

POLBORN, K ^{[1
]}

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,W-8000 MUNICH 2,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 08期

关键词：

D O I：

10.1002/anie.199009271

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By oxidative coupling of the lithiated allene 1, the title compound 2 is formed in several stereoisomeric forms. One of them cyclizes rapidly in a conrotatory ring closure to give 3, another cyclizes slowly to give 4, which was characterized by an X‐ray structure analysis. Aryl = 2,4,6‐tBu3C6H2. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

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页码：927 / 929

页数：3

相关论文

共 10 条

[1] CHIRAL BUTADIENES .10. BARRIERS TO ENANTIOMERIZATION OF 1,2,3,4-TETRAMETHYL-1,3-BUTADIENES [J].

BECHER, G ;

MANNSCHRECK, A .

CHEMISCHE BERICHTE-RECUEIL, 1983, 116 (01) :264-272

[2] CHIRAL BUTADIENES .9. PREPARATIVE ENRICHMENT OF ENANTIOMERIC 2,3,4,5-TETRABROMO-2,4-HEXADIENES BY LIQUID-CHROMATOGRAPHY [J].

BECHER, G ;

MANNSCHRECK, A .

CHEMISCHE BERICHTE-RECUEIL, 1981, 114 (06) :2365-2368

[3] CHIRAL BUTADIENES .6. HINDERED ROTATION IN PENTASUBSTITUTED AND HEXASUBSTITUTED BUTADIENES - BUTTRESSING EFFECTS [J].

BODECKER, HO ;

JONAS, V ;

KOLB, B ;

MANNSCHRECK, A ;

KOBRICH, G .

CHEMISCHE BERICHTE-RECUEIL, 1975, 108 (11) :3497-3508

[4]

COLVIN E, 1981, SILICON ORGANIC SYNT, P142

[5] STABLE CARBENOIDS .47. CHEMISTRY OF CARBENOIDS AND OTHER THERMOLABILE ORGANOLITHIUM COMPOUNDS [J].

KOBRICH, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1972, 11 (06) :473-&

[6]

Kobrich G., 1972, ANGEW CHEM, V84, P557

[7] TAUTOMERS OF 3H-PHOSPHAALLENE AND ALKYNYL-1H-PHOSPHINE [J].

MARKL, G ;

REITINGER, S .

TETRAHEDRON LETTERS, 1988, 29 (04) :463-466

[8] PHOSPHABUTATRIENE 1.2-BIS(PHOSPHAALLENYL)CYCLOBUTANE [J].

MARKL, G ;

KREITMEIER, P .

TETRAHEDRON LETTERS, 1989, 30 (30) :3939-3942

[9] PARTIAL ENANTIOMERIZATION OF AN ATROPISOMERIC BUTADIENE [J].

ROSNER, M ;

KOBRICH, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1974, 13 (11) :741-742

[10]

ROSNER M, 1974, ANGEW CHEM, V86, P775