SYNTHESIS AND PHYSICAL-PROPERTIES OF NEW CHARGE-TRANSFER SALTS DERIVED FROM E-BIS(ETHYLENETHIO)TETRATHIAFULVALENE (BET-TTF)

被引：8

作者：

TARRES, J

VECIANA, J

ROVIRA, C

机构：

[1] Institut de Ciència de Materials de Barcelona (CSIC), 08193 Bellaterra, Campus UAB

来源：

SYNTHETIC METALS | 1995年 / 70卷 / 1-3期

关键词：

D O I：

10.1016/0379-6779(94)02804-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The synthesis, characterization and physical properties of several charge transfer salts based on the organic pi-electron donor bis(ethylenethio)tetrathiafulvalene (BET-TTF) with Bi and Cu(NCS)(2)(-) anions are reported. Experimental conditions significantly affect shape and the composition of the charge-transfer solids synthesized by electrocrystallization. In fact salts with different stoichiometrics obtained from each counterion. Mixed valence salts with Br- have two water molecules in their composition The magnetic behavior of obtained salts has been studied by EPR spectroscopy. EPR parameters (g and Delta H-pp) peermit to distinguish between the different stoichiomet of a given salt

引用

页码：1167 / 1168

页数：2

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