EVALUATION OF THERMODYNAMIC PARAMETERS OF BIVALENT-METAL COMPLEXES OF 2-HYDROXYACETOPHENONETHIOSEMICARBAZONE (2-HATS)

被引:5
作者
GARG, BS
GHOSH, S
JAIN, VK
SINGH, PK
机构
[1] Department of Chemistry, University of Delhi, Delhi
关键词
D O I
10.1016/0040-6031(90)80038-Z
中图分类号
O414.1 [热力学];
学科分类号
摘要
Thermodynamic parameters (ΔG, ΔH and ΔS) and stability constants of complexes of 2-hydroxyacetophenonethiosemicarbazone (2-HATS) with Mg(II), Mn(II), Cd(II), Pb(II), Ni(II) and Cu(II) have been determined pH-metrically in 50% (v/v) aqueous dioxan. The formation constants (log βn) have been calculated using the weighted least-squares method. © 1990.
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页码:365 / 368
页数:4
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