SYNTHESIS OF [6-(1,4,7,10-TETRAAZA-12-CYCLOTRIDECYL)-1,4,8,11-TETRAAZACYCLOTETRADECANE]DINICKEL(II) PERCHLORATE AND ITS ELECTROCATALYTIC PROPERTY FOR WATER REDUCTION

被引：16

作者：

MOCHIZUKI, K

GOTOH, H

SUWABE, M

SAKAKIBARA, T

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 06期

关键词：

D O I：

10.1246/bcsj.64.1750

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new bimacrocyclic ligand, in which 13- and 14-membered rings are linked together by a C-C bond, 6-(1,4,7,10-tetraaza-12-cyclotridecyl)-1,4,8,11-tetraazacyclotetradecane (L13-14), and its dinickel(II) complex, [Ni(II)2L13-14]4+ were synthesized. The absorption spectra and cyclic voltammograms of [Ni(II)2L13-14]4+ showed that it has properties of both the 13- and 14-membered rings. Cyclic voltammetry and controlled-potential electrolysis showed that [Ni(II)2L13-14]4+ can serve as an electrocatalyst for water reduction to produce H2. The electrocatalytic efficiency for H2 production at -1.5 V was found to be as follows: [Ni(II)2L14-14]4+ (L14-14: 6,6'-bi(1,4,8,11-tetraazacyclotetradecane)) > [Ni(II)2L13-14]4+ almost-equal-to [Ni(II)L14]2+ (L14: 1,4,8,11-tetraazacyclotetradecane) >> [Ni(II)2L13-13]4+ (L13-13: 12,12'-bi(1,4,7,10-tetraazacyclotridecane)).

引用

收藏

页码：1750 / 1756

页数：7

相关论文

共 20 条

[1] CHARACTERIZATION OF 2,2'-BI-(1,4,8,11-TETRA-AZACYCLOTETRADECANE) - X-RAY STRUCTURE AND PROPERTIES OF THE DINUCLEAR COMPLEX [NI2(C20H46N8)][C1O4]4 [J].

BAREFIELD, EK ;

CHUENG, D ;

VANDERVEER, DG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (06) :302-304

[2] RING-SIZE EFFECTS ON THE FORMATION OF DICOPPER(II) AND DICOPPER(III) COMPLEXES WITH BIMACROCYCLES CONTAINING 13-MEMBERED AND 14-MEMBERED TETRAAZA SUBUNITS [J].

BUTTAFAVA, A ;

FABBRIZZI, L ;

PEROTTI, A ;

POGGI, A ;

SEGHI, B .

INORGANIC CHEMISTRY, 1984, 23 (24) :3917-3922

[3] SYNTHESIS OF 1,2-BIS(1,4,7,10-TETRA-AZADODECANYL)ETHANE, A DOUBLE-RING FULLY SATURATED MACROCYCLE CONTAINING 12-MEMBERED TETRA-AZA SUBUNITS [J].

CIAMPOLINI, M ;

MICHELONI, M ;

NARDI, N ;

VIZZA, F ;

BUTTAFAVA, A ;

FABBRIZZI, L ;

PEROTTI, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (15) :998-999

[4] ELECTROCATALYTIC PROPERTIES OF NI(CYCLAM)2+ AND NI2(BISCYCLAM)4+ WITH RESPECT TO CO2 AND H2O REDUCTION [J].

COLLIN, JP ;

JOUAITI, A ;

SAUVAGE, JP .

INORGANIC CHEMISTRY, 1988, 27 (11) :1986-1990

[5] DITOPIC RECEPTORS FOR TRANSITION-METAL IONS - A HETEROBIMETALLIC NICKEL(II) COPPER(II) BIS(MACROCYCLIC) COMPLEX AND ITS STEPWISE OXIDATION TO THE TERVALENT STATE [J].

FABBRIZZI, L ;

MONTAGNA, L ;

POGGI, A ;

KADEN, TA ;

SIEGFRIED, LC .

INORGANIC CHEMISTRY, 1986, 25 (16) :2671-2672

[6] BICYCLAM [6,6'-BI(1,4,8,11-TETRA-AZACYCLOTETRADECANE)] - A DITOPIC RECEPTOR FOR HOMO-BIMETALLIC AND HETEROBIMETALLIC COMPLEXES [J].

FABBRIZZI, L ;

MONTAGNA, L ;

POGGI, A ;

KADEN, TA ;

SIEGFRIED, LC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (11) :2631-2634

[7] STEPWISE INCORPORATION OF COPPER(II) INTO A DOUBLE-RING OCTAAZA MACROCYCLE AND CONSECUTIVE OXIDATION TO THE TRIVALENT STATE [J].

FABBRIZZI, L ;

FORLINI, F ;

PEROTTI, A ;

SEGHI, B .

INORGANIC CHEMISTRY, 1984, 23 (07) :807-813

[8] SELECTIVITY OF TETRA-AZA MACROCYCLES TOWARDS METAL SPIN STATES - HIGH-SPIN LOW-SPIN EQUILIBRIUM FOR NICKEL(II) COMPLEXES WITH 13-MEMBERED AND 14-MEMBERED LIGANDS [J].

FABBRIZZI, L .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (12) :1857-1861

[9] ELECTROCATALYTIC REDUCTION OF CARBON-DIOXIDE BY USING MACROCYCLES OF NICKEL AND COBALT [J].

FISHER, B ;

EISENBERG, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (24) :7361-7363

[10] PHOTOCHEMICAL REDUCTION OF CARBON-DIOXIDE TO CARBON-MONOXIDE IN WATER USING A NICKEL(II) TETRA-AZAMACROCYCLE COMPLEX AS CATALYST [J].

GRANT, JL ;

GOSWAMI, K ;

SPREER, LO ;

OTVOS, JW ;

CALVIN, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (09) :2105-2109