8,12-DIETHYL-2,3,7,13,17,18-HEXAMETHYL-20-PHENYLPORPHYRIN

被引：13

作者：

SENGE, MO

LIDDELL, PA

SMITH, KM

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270191010338

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C36H38N4, M(r) = 526.7, orthorhombic, Iba2, a = 12.870 (6), b = 55.71 (3), c = 7.837 (2) angstrom, V = 5619 (4) angstrom 3, Z = 8, D(x) = 1.245 Mg m-3, lambda(Mo K-alpha) = 0.7107 angstrom, mu = 0.069 mm-1, F(000) = 2256, T = 130 K, R = 0.076 for 1428 independent reflections [I > 2-sigma(I)]. The title compound consists of the slightly ruffled porphyrin macrocycle with the phenyl substituent oriented 84.6-degrees out of the plane of the N atoms.

引用

页码：581 / 583

页数：3

共 6 条

[1] NONPLANAR PORPHYRINS - X-RAY STRUCTURES OF (2,3,7,8,12,13,17,18-OCTAETHYL-5,10,15,20-TETRAPHENYLPOPHINATO)ZINC(II) AND (2,3,7,8,12,13,17,18-OCTAMETHYL-5,10,15,20-TETRAPHENYLPORPHINATO)ZINC(II) [J].

BARKIGIA, KM ;

BERBER, MD ;

FAJER, J ;

MEDFORTH, CJ ;

RENNER, MW ;

SMITH, KM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (24) :8851-8857

[2]

BARKIGIA KM, 1988, J AM CHEM SOC, V110, P7599

[3]

Cromer D.T, 1974, INT TABLES XRAY CRYS, VIV

[4]

HOPE H, 1987, THESIS U CALIFORNIA

[5]

Scheidt WR, 1987, METAL COMPLEXES TETR, P1, DOI DOI 10.1007/BFB0036789

[6]

SHELDRICK GM, 1990, SHELXTL PLUS PROGRAM

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