OXIDATION OF CIS-PINANE AND TRANS-PINANE WITH RUO4 GENERATED IN-SITU

被引：25

作者：

COUDRET, JL ^{[1
]}

WAEGEL, B ^{[1
]}

机构：

[1] FAC SCI & TECH ST JEROME,LASCO,CNRS,URA 1409,STEREOCHIM LAB,CASE 532,F-13397 MARSEILLE 20,FRANCE

来源：

INORGANICA CHIMICA ACTA | 1994年 / 222卷 / 1-2期

关键词：

RUTHENIUM COMPLEXES; OXO COMPLEXES; OXIDATION; HYDROXYLATION; ALKANES; CARBON CARBON BOND CLEAVAGE; BRIDGEHEAD REACTIVITY;

D O I：

10.1016/0020-1693(94)03900-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The products obtained by oxidation of cis- and trans-pinane (1a and 1b) by RuO4 generated in situ have been analyzed. Examination of their structure shows that two mechanisms are operating: a concerted mechanism postulated by ourselves and a more energetic mechanism considered by Bakke, which involves the development of a partial positive charge on the carbon to be oxidized.

引用

页码：115 / 122

页数：8

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