SCREW-CHAIN STRUCTURE OF 1,10-PHENANTHROLINE HYDRATE, C12H8N2-CENTER-DOT-H20

被引:36
作者
TIAN, YP
DUAN, CY
XU, XX
YOU, XZ
机构
关键词
D O I
10.1107/S010827019500549X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The X-ray analysis revealed that the title compound is an infinite 3(1) screw-chain structure with a repeat distance of 8.453 Angstrom. The O atoms of the water connect to one another around the screw axis to form the core of the chain and the o-phenanthroline molecules connect through intermolecular hydrogen bonds to these water molecules. The structure can be regarded as a screw supermolecule assembled by hydrogen bonds and is a displacive modulation of an idealized P3(1)21 parent structure.
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页码:2309 / 2312
页数:4
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