PHOTODECOUPLING OF CROSS-LINKS IN POLYMERIC GELS

被引:10
作者
LI, MY [1 ]
LIANG, RC [1 ]
REISER, A [1 ]
机构
[1] POLYTECH INST NEW YORK,INST IMAGING SCI,333 JAY ST,BROOKLYN,NY 11201
关键词
D O I
10.1021/ma00212a019
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Poly(butyl methacrylate) gels with photolabile cross-linked acyloxime units were prepared. The acyloxime moieties are scissioned on exposure to UV radiation, the cross-links decouple, and the solid material is thereby solubilized. The quantum yield of cross-link decoupling is about θ = 0.03. The physicochemical consequences of cross-link decoupling are investigated. © 1990, American Chemical Society. All rights reserved.
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页码:2704 / 2709
页数:6
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