POLYOXAZOLINES BASED ON FATTY-ACIDS

被引：40

作者：

BECK, M

BIRNBRICH, P

EICKEN, U

FISCHER, H

FRISTAD, WE

HASE, B

KRAUSE, HJ

机构：

来源：

ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1994年 / 223卷

关键词：

D O I：

10.1002/apmc.1994.052230116

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new, economic technique was developed for the production of 2-alkyl-2-oxazolines with saturated, unsaturated or OH-functionalized alkylrests. In the process the fatty acids are changed into polymerizable monomers. The cationic polymerization of fattyalkyl-2-oxazolines was investigated in unpolar solvents and in bulk. It reacts in a living mechanism. The polymerization is remarkable inert against impurities like water or ethanolamide. A reaction enthalpy of DELTAH = 85,9 kJ/mol was found for the bulk polymerization of 2-pentadecyl-2-oxazoline.

引用

页码：217 / 233

页数：17

共 20 条

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[2]

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[3]

EICKEN U, 1993, FARBE LACK, V99, P911

[4] POLYMERIZATION OF 2-OXAZOLINES .2. KINETICS OF CATIONIC POLYMERIZATION OF 2-PHENYL-2-OXAZOLINE INITIATED BY OXAZOLINIUM PERCHLORATE IN N,N-DIMETHYLACETAMIDE SOLUTION [J].