EVALUATION OF FLOW-INJECTION METHODS FOR AMMONIUM DETERMINATION IN WASTE-WATER SAMPLES

被引：50

作者：

CERDA, A ^{[1
]}

OMS, MT ^{[1
]}

FORTEZA, R ^{[1
]}

CERDA, V ^{[1
]}

机构：

[1] UNIV BALEARIC ISL,DEPT CHEM,E-07071 PALMA DE MALLORCA,SPAIN

来源：

ANALYTICA CHIMICA ACTA | 1995年 / 311卷 / 02期

关键词：

FLOW INJECTION; WASTE-WATER; WATERS; AMMONIUM;

D O I：

10.1016/0003-2670(95)00182-Y

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A comparative study of now injection methods for the determination of ammonium ion in wastewater samples is presented. It includes methods based on the Berthelot reaction and methods based on gas diffusion. Detection is either spectrophotometric or conductimetric. Analytical characteristics of each method are described in terms of reproducibility, sensitivity and selectivity. The performance of several gas permeable membranes to be used in gas-diffusion systems is discussed. The stopped flow approach is also investigated in order to improve the detection limits. Calibration graphs are obtained for each system, with and without that preconcentration step. Finally, a number of wastewater samples are analyzed using the described methods and the results are compared.

引用

页码：165 / 173

页数：9

共 16 条

[1] AN APPARATUS FOR THE DETERMINATION OF VOLATILE ANALYTES BY STOPPED-FLOW INJECTION-ANALYSIS USING AN INTEGRATED FIBER OPTIC DETECTOR
BAXTER, PJ
RUZICKA, J
CHRISTIAN, GD
[J]. TALANTA, 1994, 41 (03) : 347 - 354
[2] BERTHELOT MPE, 1959, REPERT CHIM APPL, P282
[3] SPECTROPHOTOMETRIC DETERMINATION OF AMMONIA AS INDOPHENOL
BOLLETER, WT
BUSHMAN, CJ
TIDWELL, PW
[J]. ANALYTICAL CHEMISTRY, 1961, 33 (04) : 592 - &
[4] THE MEASUREMENT OF LOW CONCENTRATIONS OF AMMONIA IN THE ATMOSPHERE BY FLOW-INJECTION ANALYSIS
BRISTOW, AW
[J]. COMMUNICATIONS IN SOIL SCIENCE AND PLANT ANALYSIS, 1991, 22 (17-18) : 1741 - 1752
[5] OPTIMIZATION OF PARAMETERS FOR GAS-DIFFUSION FLOW-INJECTION SYSTEMS
CANHAM, JS
GORDON, G
PACEY, GE
[J]. ANALYTICA CHIMICA ACTA, 1988, 209 (1-2) : 157 - 163
[6] POTENTIOMETRIC AND CONDUCTOMETRIC DETERMINATION OF AMMONIUM BY GAS-DIFFUSION FLOW-INJECTION ANALYSIS
FRENZEL, W
LIU, CY
[J]. FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1992, 342 (4-5): : 276 - 280
[7] SPECTROPHOTOMETRIC DETERMINATION OF AMMONIA - A STUDY OF A MODIFIED BERTHELOT REACTION USING SALICYLATE AND DICHLOROISOCYANURATE
KROM, MD
[J]. ANALYST, 1980, 105 (1249) : 305 - 316
[8] ZONE TRAPPING IN FLOW-INJECTION ANALYSIS - SPECTROPHOTOMETRIC DETERMINATION OF LOW-LEVELS OF AMMONIUM ION IN NATURAL-WATERS
KRUG, FJ
REIS, BF
GINE, MF
ZAGATTO, EAG
FERREIRA, JR
JACINTHO, AO
[J]. ANALYTICA CHIMICA ACTA, 1983, 151 (01) : 39 - 48
[9] SPECTROPHOTOMETRIC AND KINETICS INVESTIGATION OF BERTHELOT REACTION FOR DETERMINATION OF AMMONIA
PATTON, CJ
CROUCH, SR
[J]. ANALYTICAL CHEMISTRY, 1977, 49 (03) : 464 - 469
[10] SELECTIVITY OF REACTION AMONG CHLORINE, AMMONIA, AND SALICYLATE FOR DETERMINATION OF AMMONIA
PYM, RVE
MILHAM, PJ
[J]. ANALYTICAL CHEMISTRY, 1976, 48 (09) : 1413 - 1415

← 1 2 →