STRUCTURE OF 2-ACETOXY-1,2-DI(1-ADAMANTYL)ETHANONE

被引:1
作者
BOTT, SG
MARCHAND, AP
MCGUFFEY, AR
XING, DX
机构
[1] Department of Chemistry, University of North Texas, Denton, 76203, Texas
关键词
CRYSTAL STRUCTURE; 1,2-DI(1-ADAMANTYL)ETHENE;
D O I
10.1007/BF01796052
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The structure of 2-acetoxy-1,2-di(1-adamantyl)ethanone is reported. The steric requirements of the two adamantyl groups affect the structure in three ways-a slight elongation of the central bond, a small expansion of the angles about the central bond, and a conformation in which the C(sp(2))-connected adamantyl group virtually bisects the large substituents attached to the sp(3) carbon.
引用
收藏
页码:291 / 294
页数:4
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