NMR-DETECTION OF INTERMEDIATES DURING HOMOGENEOUS HYDROGENATION OF DIENES USING PARAHYDROGEN

被引：35

作者：

BARGON, J

KANDELS, J

KATING, P

THOMAS, A

WOELK, K

机构：

[1] Institute of Physical Chemistry, University of Bonn, D-5300 Bonn 1

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 40期

关键词：

D O I：

10.1016/S0040-4039(00)97941-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 1HNMR spectra of the reaction products of hydrogenations using parahydrogen reveal information about intermediates and thus the reaction mechanism. 2. Due to its high signal enhancement the method is uniquely suited for reactions, where the catalyst itself becomes chemically modified. © 1990.

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页码：5721 / 5724

页数：4

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