PALLADIUM-CATALYZED ADDITION OF MALONATE TYPE COMPOUNDS TO ALLENES VIA A HYDROPALLADATION PROCESS

被引：65

作者：

BESSON, L ^{[1
]}

GORE, J ^{[1
]}

GAZES, B ^{[1
]}

机构：

[1] UNIV LYON 1,CNRS,CHIM ORGAN LAB 1,F-69622 VILLEURBANNE,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 22期

关键词：

D O I：

10.1016/0040-4039(95)00655-V

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium and base-catalyzed addition of malonates and acetylacetates to allenic hydrocarbons affords allylated dicarbonyl compounds. Results account likely for an unprecedented hydropalladation process of the allenic unit which leads to a pi-allylpalladium intermediate.

引用

页码：3853 / 3856

页数：4

共 17 条

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