RHODIUM(I) SULFONATED-BDPP CATALYZED ASYMMETRIC HYDROGENATION OF IMINES IN AQUEOUS ORGANIC 2-PHASE SOLVENT SYSTEMS

被引：122

作者：

BAKOS, J ^{[1
]}

OROSZ, A ^{[1
]}

HEIL, B ^{[1
]}

LAGHMARI, M ^{[1
]}

LHOSTE, P ^{[1
]}

SINOU, D ^{[1
]}

机构：

[1] UNIV LYON 1,SYNTH ASYMETR LAB,CNRS,URA 463,F-69622 VILLEURBANNE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 23期

关键词：

D O I：

10.1039/c39910001684

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The imines ArC(Me) = NCH2Ph (Ar = Ph, 2-MeO-C6H4, 3-MeO-C6H4, 4-MeO-C6H4) are hydrogenated to the corresponding amines with extremely high enantioselectivities up to 96% under very mild conditions, using rhodium complexes associated with sulfonated bdpp.

引用

页码：1684 / 1685

页数：2

共 22 条

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