SYNTHESIS OF CUBANE-LIKE AND DOUBLE CUBANE-LIKE TUNGSTEN-COPPER-SULFUR CLUSTERS FROM THE BUTTERFLY CLUSTER [CU2S3W(O)(PPH3)3]

被引：38

作者：

DU, SW ^{[1
]}

ZHU, NY ^{[1
]}

CHEN, PC ^{[1
]}

WU, XT ^{[1
]}

机构：

[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,FUZHOU LAB STRUCT CHEM,FUJIAN 350002,PEOPLES R CHINA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 08期

关键词：

D O I：

10.1002/anie.199210851

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The denticity of the thiolato ligand decides whether the cuband-like cluster 1 or the bicubane-like cluster 2 is obtained in the reaction of copper thiolates with the "butterfly" cluster [Cu2S3W(O)(PPh3)3]. This could also be confirmed by further cluster syntheses. Tungsten copper sulfur clusters such as 1 and 2 are of interest, inter alia, as models for the active centers of some enzymes.

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页码：1085 / 1087

页数：3

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