CADMIUM BIS(ALKYLTHIOLATE) COMPLEXES AS PRECURSORS FOR CADMIUM-SULFIDE - A MILD ROUTE TO HAWLEYITE

被引：12

作者：

KRAUTER, G

REES, WS

机构：

[1] GEORGIA INST TECHNOL, SCH CHEM & BIOCHEM, ATLANTA, GA 30332 USA

[2] GEORGIA INST TECHNOL, SCH MAT SCI, ATLANTA, GA 30332 USA

[3] GEORGIA INST TECHNOL, INST MOLEC DESIGN, ATLANTA, GA 30332 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1995年 / 5卷 / 08期

关键词：

D O I：

10.1039/jm9950501265

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The preparation, characterization and thermolysis of Cd(SR)(2) (R = Pr-i, Bu(t), Bz), [Cd(SPri)(2) . 1-methylimidazole] and {[Cd(SBz)(2)](2) . 1-methylimidazole} are reported. The volatile organosulfur reaction co-products were identified as RSR, or its subsequent secondary decomposition products. Hawleyite is formed from Cd(SBz)(2) at 300 degrees C, 0.1 atm, 4 h; whereas the other two Cd(SR), examples produce the expected Greenockite.

引用

页码：1265 / 1267

页数：3

共 57 条

[1] GROWTH OF II-VI THIN-FILMS FROM SINGLE-SOURCE PRECURSORS BASED ON STERICALLY ENCUMBERED SITEL LIGANDS [J].