PREPARATION OF OXONANES AND AZONANES BY OXIDATIVE RING EXPANSION - SYNTHESIS OF OBTUSAN

被引：17

作者：

BROWN, DS

ELLIOTT, MC

MOODY, CJ

MOWLEM, TJ

机构：

[1] LOUGHBOROUGH UNIV TECHNOL, DEPT CHEM, LOUGHBOROUGH LE11 3TU, LEICS, ENGLAND

[2] SHELL RES LTD, SITTINGBOURNE RES CTR, SITTINGBOURNE ME9 8AG, KENT, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 09期

关键词：

D O I：

10.1039/p19950001137

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxonanes can be readily prepared from phthalans by a 3-step procedure involving Birch reduction, selective hydrogenation and oxidation. 2-Ethyl-9-pentyloxonane-3,8-dione has been deoxygenated to give obtusan. The method has been applied to the synthesis of an azonane.

引用

收藏

页码：1137 / 1144

页数：8

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