HYDROGENATION OF HIGHLY UNSATURATED-HYDROCARBONS OVER HIGHLY DISPERSED PD CATALYST .2. LIGAND EFFECT OF PIPERIDINE

被引：73

作者：

BOITIAUX, JP

COSYNS, J

VASUDEVAN, S

机构：

[1] Inst Francais du Petrole, Reuil-Malmaison, Fr, Inst Francais du Petrole, Reuil-Malmaison, Fr

来源：

APPLIED CATALYSIS | 1985年 / 15卷 / 02期

关键词：

CATALYSIS; -; CATALYSTS; Palladium; OLEFINS;

D O I：

10.1016/S0166-9834(00)81845-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrogenation of highly unsaturated hydrocarbons like 1-butyne, 1,3-butadiene and isoprene was shown to be sensitive to metallic dispersion. Addition of an electrodonating compound like piperidine in the reaction mixture increases the hydrogenation rate and the selectivity for the formation of olefin. This effect is explained by a decomplexation or ligand effect.

引用

页码：317 / 326

页数：10

共 15 条

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