REACTION OF 3-METHYL-2-CYCLOPENTEN-1-ONE N,N-DIMETHYLHYDRAZONE WITH ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS - A NOVEL SYNTHESIS OF BICYCLIC COMPOUNDS

被引：2

作者：

MATSUMIYA, K ^{[1
]}

GUO, YP ^{[1
]}

YAMASHITA, M ^{[1
]}

机构：

[1] DOSHISHA UNIV, DEPT APPL CHEM, KAMIKYO KU, KYOTO 602, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 07期

关键词：

D O I：

10.1246/cl.1992.1201

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3-Methyl-2-cyclopenten-1-one N,N-dimethylhydrazone reacted with methyl vinyl ketone or acrylic acid derivatives to give a new bicyclic bifunctional compound in good yield in a polar aprotic solvent such as dimethylformamide.

引用

页码：1201 / 1202

页数：2

共 6 条

[1]

COREY EJ, 1978, TETRAHEDRON LETT, P4597

[2] SYNTHETIC ROUTES TO POLYFUNCTIONAL MOLECULES VIA METALLATED DIMETHYLHYDRAZONES [J].

COREY, EJ ;

ENDERS, D .

CHEMISCHE BERICHTE-RECUEIL, 1978, 111 (04) :1362-1383

[3] GENERATION AND SYNTHETIC USE OF METALLATED DIMETHYLHYDRAZONES REGION AND STEREOSELECTIVE ALKYLATION OF CARBONYL-COMPOUNDS [J].

COREY, EJ ;

ENDERS, D .

CHEMISCHE BERICHTE-RECUEIL, 1978, 111 (04) :1337-1361

[4] ALPHA-ALKYLATION OF LITHIATED (2E, 4E)-2,4-ALKADIENAL DIMETHYLHYDRAZONES - PREPARATION OF ALPHA-ALKYLATED (3E, 5Z)-3,5-ALKADIENAL DIMETHYLHYDRAZONES [J].

MATSUMIYA, K ;

NAKANO, K ;

SUEMITSU, R ;

YAMASHITA, M .

CHEMISTRY LETTERS, 1988, (11) :1837-1838

[5] A CONVENIENT SYNTHESIS OF DIKETONES VIA ALKYLATION OF ALKYL METHYL KETONE DIMETHYLHYDRAZONES [J].

YAMASHITA, M ;

MATSUMIYA, K ;

MORIMOTO, H ;

SUEMITSU, R .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1989, 62 (05) :1668-1670

[6] ORGANIC-SYNTHESIS VIA DIALKYLHYDRAZONES .4. ALPHA-ALKYLATION OF LITHIATED ALPHA,BETA-UNSATURATED ALDEHYDE N,N-DIMETHYLHYDRAZONES - SYNTHESIS OF ALPHA-ALKYLATED BETA,GAMMA-UNSATURATED ALDEHYDES [J].

YAMASHITA, M ;

MATSUMIYA, K ;

NAKANO, K ;

SUEMITSU, R .

CHEMISTRY LETTERS, 1988, (07) :1215-1218

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