A 1ST STEP TOWARD THE PHOSPHORUS ANALOGS OF POLYTHIOPHENES

被引：68

作者：

BEVIERRE, MO ^{[1
]}

MERCIER, F ^{[1
]}

RICARD, L ^{[1
]}

MATHEY, F ^{[1
]}

机构：

[1] ECOLE POLYTECH,DCPH,CHIM PHOSPHORE & MET TRANSIT LAB,CNRS,F-91128 PALAISEAU,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 06期

关键词：

D O I：

10.1002/anie.199006551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetramerization with α‐thienyl migration to give 2 and subsequent cleavage of the P‐P bonds of the dimer with sodium afforded access, starting from 1, to a biphospholyl dianion which is isoelectronic with α‐sexithienyl. Its further derivatization yielded a W‐ and a Mo‐complex, whose X‐ray structure analyses afforded important information about the electronic structure of the chain. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：655 / 657

页数：3

共 25 条

[1] CHARACTERIZATION OF THE PARENT PHOSPHOLE AND PHOSPHOLYL ANION AND SOME OF THEIR C-SUBSTITUTED DERIVATIVES BY H-1 AND C-13 NMR-SPECTROSCOPY [J].

CHARRIER, C ;

MATHEY, F .

TETRAHEDRON LETTERS, 1987, 28 (42) :5025-5028

[2] SYNTHESIS AND CRYSTAL-STRUCTURE OF A PHOSPHOLYL ANION [J].

DOUGLAS, T ;

THEOPOLD, KH .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (10) :1367-1368

[3]

DOUGLAS T, 1989, ANGEW CHEM, V101, P1394

[4]

FICHOU D, 1989, SYNTHETIC MET, V28, pC723, DOI 10.1016/0379-6779(89)90596-1

[5]

FICHOU D, 1989, SYNTHETIC MET, V28, pC729, DOI 10.1016/0379-6779(89)90597-3

[6]

FICHOU D, 1988, CHEMTRONICS, V3, P176

[7] PHOTORESPONSE OF POLYACETYLENE JUNCTIONS - A GEMINATE RECOMBINATION MODEL [J].

GALLUZZI, F ;

SCHWARZ, M .

CHEMICAL PHYSICS LETTERS, 1984, 105 (01) :95-98

[8]

GARNIER F, 1989, SYNTHETIC MET, V28, pC705, DOI 10.1016/0379-6779(89)90594-8

[9] ELECTROCHEMICALLY GROWN POLYTHIOPHENE AND POLY(3-METHYLTHIOPHENE) ORGANIC PHOTOVOLTAIC CELLS [J].

GLENIS, S ;

HOROWITZ, G ;

TOURILLON, G ;

GARNIER, F .

THIN SOLID FILMS, 1984, 111 (02) :93-103

[10]

GUIMON C, 1979, NOUV J CHIM, V3, P725

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