X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF CARBON-FIBER SURFACES .13. VALENCE-BAND STUDIES OF OXIDIZED FIBERS INTERPRETED BY X-ALPHA CALCULATIONS

被引：45

作者：

XIE, YM ^{[1
]}

SHERWOOD, PMA ^{[1
]}

机构：

[1] KANSAS STATE UNIV AGR & APPL SCI,DEPT CHEM,WILLARD HALL,MANHATTAN,KS 66506

来源：

CHEMISTRY OF MATERIALS | 1991年 / 3卷 / 01期

关键词：

D O I：

10.1021/cm00013a034

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The results of valence-band X-ray photoelectron spectroscopy (XPS) of oxidized carbon fibers are interpreted by X-alpha calculations on model compounds based upon oxidized coronene fragments. The results indicate that valence-band XPS can distinguish between ether/epoxide and hydroxide surface functionality and that the valence-band region is potentially more sensitive to differences in surface functionality than the core region. XPS data for quinone and hydroquinone with the valence-band region interpreted by X-alpha calculations are presented and related to the carbon fiber spectra.

引用

页码：164 / 168

页数：5

共 20 条

[1] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF ELECTRODE SURFACES USING A NEW CONTROLLED TRANSFER TECHNIQUE .2. RESULTS FOR A MOLYBDENUM ELECTRODE AND THE CURVE FITTING PROCEDURE [J].

ANSELL, RO ;

DICKINSON, T ;

POVEY, AF ;

SHERWOOD, PMA .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1979, 98 (01) :79-89

[2] A NON-EMPIRICAL LCAO MO SCF AND EXPERIMENTAL INVESTIGATION ON THE CORE-IONIZED STATES OF ACETYLACETONE AND SOME OF ITS ENOL TAUTOMERS [J].

CLARK, DT ;

HARRISON, A .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1981, 23 (01) :39-53

[3] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF CARBON-FIBER SURFACES .6. PILOT-PLANT SURFACE-TREATMENT AND EPOXY-RESIN COMPOSITES [J].

HARVEY, J ;

KOZLOWSKI, C ;

SHERWOOD, PMA .

JOURNAL OF MATERIALS SCIENCE, 1987, 22 (05) :1585-1596

[4] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF CARBON-FIBER SURFACES .8. A COMPARISON OF TYPE-I AND TYPE-II FIBERS AND THEIR INTERACTION WITH THIN RESIN FILMS [J].

KOZLOWSKI, C ;

SHERWOOD, PMA .

CARBON, 1987, 25 (06) :751-760

[5] X-RAY PHOTOELECTRON-SPECTROSCOPIC STUDIES OF CARBON-FIBRE SURFACES .5. THE EFFECT OF PH ON SURFACE OXIDATION [J].

KOZLOWSKI, C ;

SHERWOOD, PMA .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1985, 81 :2745-2756

[6] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF CARBON-FIBER SURFACES VII-ELECTROCHEMICAL TREATMENT IN AMMONIUM SALT ELECTROLYTES [J].

KOZLOWSKI, C ;

SHERWOOD, PMA .

CARBON, 1986, 24 (03) :357-363

[7] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF CARBON-FIBER SURFACES .4. THE EFFECT OF ELECTROCHEMICAL TREATMENT IN NITRIC-ACID [J].

KOZLOWSKI, C ;

SHERWOOD, PMA .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1984, 80 :2099-&

[8]

PIREAUX JJ, 1981, ACS SYM SER, V162, P169, DOI DOI 10.1021/bk-1981-0162.ch013

[9] X-RAY PHOTO-ELECTRON SPECTROSCOPIC STUDIES OF CARBON-FIBER SURFACES .1. CARBON-FIBER SPECTRA AND THE EFFECTS OF HEAT-TREATMENT [J].

PROCTOR, A ;

SHERWOOD, PMA .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1982, 27 (01) :39-56

[10] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF CARBON-FIBER SURFACES .3. INDUSTRIALLY TREATED FIBERS AND THE EFFECT OF HEAT AND EXPOSURE TO OXYGEN [J].

PROCTOR, A ;

SHERWOOD, PMA .

SURFACE AND INTERFACE ANALYSIS, 1982, 4 (05) :212-219

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